SURFACE CHEMISTRY

Which of the following process does not occur at the interface of phases?

• crystallisation

• heterogenous catalysis

• homogeneous catalysis

• corrosion

At the equilibrium position in the process of adsorption ___________.

• ΔH > 0

• ΔH = TΔS

• ΔH > TΔS

• ΔH < TΔS

Which of the following interface cannot be obtained?

• liquid-liquid

• solid-liquid

• liquid-gas

• gas-gas

The term ‘sorption’ stands for ____________.

• absorption

• adsorption

• both absorption and adsorption

• desorption

Extent of physisorption of a gas increases with ___________.

• increase in temperature.

• decrease in temperature.

• decrease in surface area of adsorbent.

• decrease in strength of van der Waals forces.

Extent of adsorption of adsorbate from solution phase increases with ________.

• increase in amount of adsorbate in solution.

• decrease in surface area of adsorbent.

• increase in temperature of solution.

• decrease in amount of adsorbate in solution.

Which one of the following is not applicable to the phenomenon of adsorption?

• ΔH > 0

• ΔG < 0

• ΔS < 0

• ΔH < 0

Which of the following is not a favourable condition for physical adsorption?

• high pressure

• negative ΔH

• higher critical temperature of adsorbate

• high temperature

Physical adsorption of a gaseous species may change to chemical adsorption with ______________.

• decrease in temperature

• increase in temperature

• increase in surface area of adsorbent

• decrease in surface area of adsorbent

In physisorption adsorbent does not show specificity for any particular gas because ______________.

• involved van der Waals forces are universal.

• gases involved behave like ideal gases.

• enthalpy of adsorption is low.

• it is a reversible process.