Hybridization and Complex Geometry in Coordination Compounds

Hybridization and Complex Geometry in Coordination Compounds

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Flashcard

Chemistry

12th Grade

Hard

Created by

leena Varghese

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9 questions

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1.

FLASHCARD QUESTION

Front

What is the oxidation state of iron (Fe) in both [FeCl6]4- and [Fe(CN)6]4- complexes?

Back

+2 in both complexes

2.

FLASHCARD QUESTION

Front

What is the electronic configuration of the Fe2+ ion?

Back

[Ar] 3d6 4s0

3.

FLASHCARD QUESTION

Front

A complex with a spin magnetic moment of 4.9 BM (Bohr Magnetons) indicates the presence of how many unpaired electrons?

Back

4

4.

FLASHCARD QUESTION

Front

What is the hybridization of the central metal ion in [FeCl6]4-?

Back

sp3d2

5.

FLASHCARD QUESTION

Front

What is the hybridization of [FeCl6]4- and [Fe(CN)6]4- respectively, given their spin magnetic moments are 4.9 BM and 0 BM?

Back

sp3d2 and d2sp3

6.

FLASHCARD QUESTION

Front

Which type of complex is formed when inner d-orbitals are utilized for hybridization, resulting in all electrons being paired?

Back

Inner orbital complex

7.

FLASHCARD QUESTION

Front

A complex with a non-zero spin magnetic moment typically indicates which characteristic?

Back

It contains unpaired electrons.

8.

FLASHCARD QUESTION

Front

What is the hybridization of [NiCl4]2- and [Ni(CN)4]2- respectively, given their spin magnetic moments are 2.8 BM and 0 BM?

Back

sp3 and dsp2

9.

FLASHCARD QUESTION

Front

What are the geometries of [NiCl4]2- and [Ni(CN)4]2- respectively, based on their hybridizations?

Back

Tetrahedral and Square Planar

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